[η5:η1-(3,6-tBu2Flu)SiMe2NtBu]Y(η1 -NC5H6)(py)2: A 1,4-Hydride-Addition Product 
to Pyridine that Provides Evidence for the First Fluorenyl(hydrido)metal (Group 
3) Complex

Kirillov, Evgueni; Lehmann, Christian W.; Razavi, Abbas; Carpentier, Jean-François

doi:10.1002/ejic.200300837

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[η⁵:η¹-(3,6-tBu₂Flu)SiMe₂NtBu]Y(η¹ -NC₅H₆)(py)₂: A 1,4-Hydride-Addition Product to Pyridine that Provides Evidence for the First Fluorenyl(hydrido)metal (Group 3) Complex

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Lehmann, Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Kirillov, E., Lehmann, C. W., Razavi, A., & Carpentier, J.-F. (2004). [η⁵:η¹-(3,6-tBu₂Flu)SiMe₂NtBu]Y(η¹ -NC₅H₆)(py)₂: A 1,4-Hydride-Addition Product to Pyridine that Provides Evidence for the First Fluorenyl(hydrido)metal (Group 3) Complex. European Journal of Inorganic Chemistry, 2004(5), 943-945. doi:10.1002/ejic.200300837.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-9737-2

Abstract

Reaction of pyridine with the “constrained geometry” fluorenyl(hydrido)yttrium complex {[(3,6‐tBu₂Flu)SiMe₂NtBu]Y(H)(THF)}₂ selectively gives the 1,4‐addition product [η⁵:η¹‐(3,6‐tBu₂Flu)SiMe₂NtBu]Y(η¹‐NC₅H₆)(py)₂, which was characterized by single‐crystal X‐ray diffraction and ¹H and ¹³C NMR spectroscopy.