Stereoselective ring-opening polymerization of racemic lactide using 
alkoxy-amino-bis(phenolate) group 3 metal complexes

Cai, Chen-Xin; Amgoune, Abderramane; Lehmann, Christian W.; Carpentier, Jean-François

doi:10.1039/B314030J

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Stereoselective ring-opening polymerization of racemic lactide using alkoxy-amino-bis(phenolate) group 3 metal complexes

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Lehmann, Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Cai, C.-X., Amgoune, A., Lehmann, C. W., & Carpentier, J.-F. (2004). Stereoselective ring-opening polymerization of racemic lactide using alkoxy-amino-bis(phenolate) group 3 metal complexes. Chemical Communications, (3), 330-331. doi:10.1039/B314030J.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-969D-4

Abstract

Polymerization of racemic lactide initated by alkyl- and amido-yttrium complexes of a non-chiral tetradentate alkoxy-amino-bis(phenolate) ligand proceeds rapidly, in a controlled manner, to give heterotactic-rich polylactic acid.