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Dynamics of Silicate Species in Solution Studied by Mass Spectrometry with Isotopically Labeled Compounds

MPS-Authors
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Pelster,  Stefan Alexander
Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Weimann,  Bruno
Service Department Ziegler (IT), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schaack,  Bernd Bastian
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schrader,  Wolfgang
Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schüth,  Ferdi
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Pelster, S. A., Weimann, B., Schaack, B. B., Schrader, W., & Schüth, F. (2007). Dynamics of Silicate Species in Solution Studied by Mass Spectrometry with Isotopically Labeled Compounds. Angewandte Chemie International Edition, 46(35), 6674-6677. doi:10.1002/anie.200701927.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-91EF-9
Abstract
Concerted exchange of four and three Si atoms is respectively responsible for interconversion of cubic octameric (picture: quality of a fit for single‐ (A), two‐ (B), and four‐atom exchange (C); C fits the experimental pattern best) and prismatic hexameric silicate species in solution according to mass spectrometry with isotopically labeled compounds. These findings have important implications for nucleation and growth processes of zeolites and other silicates.