English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Primary‐Amine‐Catalyzed Enantioselective Intramolecular Aldolizations

MPS-Authors
/persons/resource/persons59143

Zhou,  Jian
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons59078

Wakchaure,  Vijay
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58764

List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Zhou, J., Wakchaure, V., Kraft, P., & List, B. (2008). Primary‐Amine‐Catalyzed Enantioselective Intramolecular Aldolizations. Angewandte Chemie International Edition, 47(40), 7656-7658. doi:10.1002/anie.200802497.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-90D9-0
Abstract
Aldol cyclodehydration of 4‐substituted‐2,6‐heptanediones leads to enantiomerically enriched 5‐substituted‐3‐methyl‐2‐cyclohexene‐1‐ones, which serve as perfume ingredients and valuable synthetic building blocks. Primary amines derived from cinchona alkaloids in combination with acetic acid are efficient catalysts for this transformation, which deliver both enantiomers of the celery ketone.