Convenient synthesis of deuterated aluminium hydrides

Pawelke, Roland H.; Felderhoff, Michael; Weidenthaler, Claudia; Schüth, Ferdi

doi:10.1016/j.scriptamat.2008.04.042

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Convenient synthesis of deuterated aluminium hydrides

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Pawelke, Roland H.
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Felderhoff, Michael
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Weidenthaler, Claudia
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Schüth, Ferdi
Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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引用

Pawelke, R. H., Felderhoff, M., Weidenthaler, C., & Schüth, F. (2008). Convenient synthesis of deuterated aluminium hydrides. Scripta Materialia, 59(5), 515-517. doi:10.1016/j.scriptamat.2008.04.042.

引用: https://hdl.handle.net/11858/00-001M-0000-000F-9061-B

要旨

We describe the ball-milling synthesis of alkali metal deuterides from commercial lithium aluminium deuteride. This reaction principle was exemplified by the mechanochemical synthesis of NaAlD₄ and KAlD₄. NaAlD₄ was prepared on the multi-gram scale by this procedure and purified by standard wet-chemical separation. Pure NaAlD₄ was obtained and used for the synthesis of Ca(AlD₄)₂. The formation of all products was verified by X-ray diffraction.