Organocatalytic Asymmetric Transferhydrogenation of β-Nitroacrylates: Accessing 
β2-Amino Acids

Martin, Nolwenn J. A.; Cheng, Xu; List, Benjamin

doi:10.1021/ja8069852

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Organocatalytic Asymmetric Transferhydrogenation of β-Nitroacrylates: Accessing β²-Amino Acids

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Martin, Nolwenn J. A.
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Cheng, Xu
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Martin, N. J. A., Cheng, X., & List, B. (2008). Organocatalytic Asymmetric Transferhydrogenation of β-Nitroacrylates: Accessing β²-Amino Acids. Journal of the American Chemical Society, 130(42), 13862-13863. doi:10.1021/ja8069852.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-9039-9

Abstract

We describe a highly efficient and enantioselective Hantzsch ester mediated conjugate reduction of β-nitroacrylates that is catalyzed by a Jacobsen thiourea catalyst as a key step in a new route to optically active β²-amino acids.