Peri-Diaurated Naphthalene: Synthesis and Reactions of a New Class of 
Organogold(I) Complexes Containing Bridging, Dianionic Naphthalenediyl Ligands

Meyer, Nadine; Lehmann, Christian W.; Lee, Terence K.-M.; Rust, Jörg; Yam, Vivian W.-W.; Mohr, Fabian

doi:10.1021/om9002335

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Peri-Diaurated Naphthalene: Synthesis and Reactions of a New Class of Organogold(I) Complexes Containing Bridging, Dianionic Naphthalenediyl Ligands

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Lehmann, Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Rust, Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Meyer, N., Lehmann, C. W., Lee, T.-K.-M., Rust, J., Yam, V.-W.-W., & Mohr, F. (2009). Peri-Diaurated Naphthalene: Synthesis and Reactions of a New Class of Organogold(I) Complexes Containing Bridging, Dianionic Naphthalenediyl Ligands. Organometallics, 28(10), 2931-2934. doi:10.1021/om9002335.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8EB7-D

Abstract

The dinuclear gold(I) compound [Au₂(μ-C₁₀H₆){μ-Ph₂P(CH₂)₂PPh₂}] was prepared in high yield by the reaction of 1,8-bis(trimethylstannyl)naphthalene with [Au₂Cl₂(μ-Ph₂P(CH₂)₂PPh₂)]. Oxidative addition with halogens results in the formation of the dihalodigold(II) complexes [Au₂(X)₂(μ-C₁₀H₆){μ-Ph₂P(CH₂)₂PPh₂}] (X = Cl, Br, I) containing a gold−gold bond.