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Journal Article

Catalytic Asymmetric Transacetalization

MPS-Authors
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Čorić,  Ilija
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Vellalath,  Sreekumar
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Čorić, I., Vellalath, S., & List, B. (2010). Catalytic Asymmetric Transacetalization. Journal of the American Chemical Society, 132(25), 8536-8537. doi:10.1021/ja102753d.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8E15-8
Abstract
A catalytic enantioselective transacetalization has been developed. The chiral phosphoric acid TRIP was demonstrated to be an efficient and highly enantioselective catalyst for the activation of O,O-acetals. The reaction enables the asymmetric synthesis of acetals with the acetal carbon as the only stereogenic center.