English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Evidence for a Non-Concerted, Dissoziative Mechanism of the Palladium-Catalyzed "Enolate Claisen Rearrangement" of Allylic Esters

MPS-Authors
/persons/resource/persons58974

Schrader,  Wolfgang
Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Braun, M., Meletis, P., & Schrader, W. (2010). Evidence for a Non-Concerted, Dissoziative Mechanism of the Palladium-Catalyzed "Enolate Claisen Rearrangement" of Allylic Esters. European Journal of Organic Chemistry, (28), 5369-5372. doi:10.1002/ejoc.201000874.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-8D3B-B
Abstract
Dissociation into carboxylic‐acid dianions and palladium complexes rather than a concerted [3,3]‐sigmatropic rearrangement occurs upon exposure of the lithiumenolate derived from allyl phenylacetate tocatalytic Pd0. Only after the fragments escaped from the solvent cage, they combine under carbon‐carbon‐bond formation and give the allylated carboxylic acid.