English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Cyclodehydrogenation of poly(perylene) to poly(quaterrylene): Toward poly(peri-naphthalene)

MPS-Authors
/persons/resource/persons47890

Former,  C.
MPI for Polymer Research, Max Planck Society;

/persons/resource/persons47960

Grimsdale,  Andrew C.
MPI for Polymer Research, Max Planck Society;

/persons/resource/persons48459

Müllen,  Klaus
MPI for Polymer Research, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Former, C., Becker, S., Grimsdale, A. C., & Müllen, K. (2002). Cyclodehydrogenation of poly(perylene) to poly(quaterrylene): Toward poly(peri-naphthalene). Macromolecules, 35(5), 1576-1582.


Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-667F-B
Abstract
Cyclodehydrogenation of soluble polyperylenes gives polymers containing predominantly quaterrylene units by spectral analysis. Evidence for larger rylene units is also seen. These polymers represent important intermediates toward a poly(peri- naphthalene) (PPN). Reactions on model compounds suggest that the insolubility of polymers with larger rylene units is predominantly due to the rigidity of the polymer backbone.