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Journal Article

Like-charge colloid-polyelectrolyte complexation

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons48420

Messina,  R.
MPI for Polymer Research, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons48054

Holm,  Christian
MPI for Polymer Research, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons48227

Kremer,  Kurt
MPI for Polymer Research, Max Planck Society;

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Citation

Messina, R., Holm, C., & Kremer, K. (2002). Like-charge colloid-polyelectrolyte complexation. Journal of Chemical Physics, 117(6), 2947-2960.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-6560-8
Abstract
We investigate the complexation of a highly charged sphere with a long flexible polyelectrolyte, both negatively charged in a salt-free environment. Electroneutrality is insured by the presence of divalent counterions. Using molecular dynamics within the framework of the primitive model, we consider different Coulomb coupling regimes. At strong Coulomb coupling we find that the adsorbed chain is always confined to the colloidal surface but forms different conformations that depend on the linear charge density of the chain. A mechanism involving the polyelectrolyte overcharging is proposed to explain these structures. At intermediate Coulomb coupling, the chain conformation starts to become three-dimensional, and we observe multilayering of the highly charged chain while for lower charge density the chain wraps around the colloid. At weak Coulomb coupling, corresponding to an aqueous solvent, we still find like-charge complexation. In this latter case the chain conformation exhibits loops. (C) 2002 American Institute of Physics.