Structure analysis of adsorbed star-like polymers with GISAS and SFM

Wolkenhauer, M.; Müller-Buschbaum, P.; Wunnicke, O.; Stamm, Manfred; Roovers, J.; von Krosigk, G.; Cubitt, R.

doi:10.1007/s003390201884

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Structure analysis of adsorbed star-like polymers with GISAS and SFM

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Wolkenhauer, M.
MPI for Polymer Research, Max Planck Society;

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Wolkenhauer, M., Müller-Buschbaum, P., Wunnicke, O., Stamm, M., Roovers, J., von Krosigk, G., et al. (2002). Structure analysis of adsorbed star-like polymers with GISAS and SFM. Applied Physics A, 74, S433-S435. doi:10.1007/s003390201884.

Cite as: https://hdl.handle.net/11858/00-001M-0000-000F-648E-C

Abstract

The lateral structures of dried adsorbed binary mixtures of star polymers were investigated. Blends of protonated and deuterated polybutadiene stars were prepared from cyclohexane solutions and adsorbed onto silicon substrates. The number of arms and the molecular weight of the arms was varied. With grazing incidence small angle scattering techniques (GISAS) and scanning force microscopy (SFM), different dominant in-plane length scales were determined. The morphology of these structures is dominated by blob-like structures created from single stars or agglomerates of star polymers.