Synthesis and properties of copolymers with tailored sequence distribution by 
controlled/living radical polymerization

Lutz, J. F.; Pakula, Tadeusz; Matyjaszewski, K.

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Synthesis and properties of copolymers with tailored sequence distribution by controlled/living radical polymerization

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http://pubman.mpdl.mpg.de/cone/persons/resource/persons48541

Pakula, Tadeusz
MPI for Polymer Research, Max Planck Society;

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Lutz, J. F., Pakula, T., & Matyjaszewski, K. (2003). Synthesis and properties of copolymers with tailored sequence distribution by controlled/living radical polymerization. ACS Symposium Series, Advances in Controlled/Living Radical Polymerization, 854, 268-282.

Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-635A-8

Abstract

The control of the overall composition and the sequence distribution in copolymers with both linear and branched architectures is described. The synthesis of alternating and gradient copolymers as well as graft copolymers with statistical, gradient and block architectures was accomplished by controlled/living radical polymerization (atom transfer radical polymerization and reversible addition-fragmentation transfer polymerization). The properties of these tailored copolymers indicate that adjustment of sequence distribution at the molecular level has important effects on the macroscopic properties of the obtained polymeric materials.