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Miktoarm block copolymer formation via ionic interactions

MPG-Autoren
http://pubman.mpdl.mpg.de/cone/persons/resource/persons47884

Floudas,  G.
MPI for Polymer Research, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons48541

Pakula,  Tadeusz
MPI for Polymer Research, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons48305

Lieser,  Günter
MPI for Polymer Research, Max Planck Society;

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Zitation

Pispas, S., Floudas, G., Pakula, T., Lieser, G., Sakellariou, S., & Hadjichristidis, N. (2003). Miktoarm block copolymer formation via ionic interactions. Macromolecules, 36(3), 759-763.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-000F-628E-B
Zusammenfassung
Blends of functionalized polystyrenes (3NPS) having three dimethylamino groups {N(CH3)(2)} at one end, with sulfonic acid end-capped polyisoprenes (HO3SPI) were prepared in a ratio of N(CH3)(2)/SO3H = 1. The morphology of these blends was studied by small-angle X-ray scattering and transmission electron microscopy and the associated dynamics by rheology. The results of the microdomain investigation, as well as of the associated dynamics, provide unambiguous evidence for controlled miktoarm star block copolymer formation via ionic interactions.