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Organic nanoparticles with polypropyleneoxide chains as support for metallocene catalysts: Ethylene homopolymerization and ethylene/alpha-olefin copolymerization

MPG-Autoren
http://pubman.mpdl.mpg.de/cone/persons/resource/persons48099

Jang,  Y. J.
MPI for Polymer Research, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons48496

Nenov,  N.
MPI for Polymer Research, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons48187

Klapper,  Markus
MPI for Polymer Research, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons48459

Müllen,  Klaus
MPI for Polymer Research, Max Planck Society;

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Zitation

Jang, Y. J., Nenov, N., Klapper, M., & Müllen, K. (2003). Organic nanoparticles with polypropyleneoxide chains as support for metallocene catalysts: Ethylene homopolymerization and ethylene/alpha-olefin copolymerization. Polymer Bulletin, 50(5-6), 343-350.


Zitierlink: http://hdl.handle.net/11858/00-001M-0000-000F-61C9-D
Zusammenfassung
Novel organic nanoparticles functionalized with nucleophilic polypropyleneoxide (PPO) chains on their surfaces for supporting metallocene catalysts in heterogeneous olefin polymerization are presented. The nanoparticles (60-100 nm) were obtained by miniemulsion polymerization of styrene, divinylbenzene and PPO functionalized styrene. It is demonstrated that Me2Si(w2MeBenzInd)(2)ZrCl2/MAO supported on these nanoparticles is suitable for the homopolymerization of ethylene, resulting in excellent product morphologies and high activities. It is shown that by varying the MAO/Zr ratios and Zr concentrations the activities and productivities of the catalysts as well as the qualities of the polyethylene products can be tuned. These new supported catalysts are also suitable for the copolymerization of ethylene with several comonomers (1-hexene, 1-octene, 1-decene or norbornene). As the obtained product properties like crystallinity, melting temperature or bulk density match the results of silica supported systems, these organic nanoparticles can be considered as alternative carriers in comparison to the established inorganic ones.