de.mpg.escidoc.pubman.appbase.FacesBean
English
 
Help Guide Disclaimer Contact us Login
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Toward a Light-Driven Motorized Nanocar: Synthesis and Initial Imaging of Single Molecules

MPS-Authors
http://pubman.mpdl.mpg.de/cone/persons/resource/persons21880

Mielke,  Johannes
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons21925

Villagómez Ojeda,  Carlos J.
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons22056

Saywell,  Alexander
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

http://pubman.mpdl.mpg.de/cone/persons/resource/persons21573

Grill,  Leonhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

Locator
There are no locators available
Fulltext (public)
There are no public fulltexts available
Supplementary Material (public)
There is no public supplementary material available
Citation

Chiang, P.-T., Mielke, J., Godoy, J., Guerrero, J. M., Alemany, L. B., Villagómez Ojeda, C. J., et al. (2012). Toward a Light-Driven Motorized Nanocar: Synthesis and Initial Imaging of Single Molecules. ACS Nano, 6(1), 592-597. doi:10.1021/nn203969b.


Cite as: http://hdl.handle.net/11858/00-001M-0000-000F-421E-3
Abstract
A second generation motorized nanocar was designed, synthesized, and imaged. To verify structural integrity, NMR-based COSY, NOESY, DEPT, HSQC, and HMBC experiments were conducted on the intermediate motor. All signals in 1H NMR were unambiguously assigned, and the results were consistent with the helical structure of the motor. The nanocar was deposited on a Cu(111) surface, and single intact molecules were imaged by scanning tunneling microscopy (STM) at 5.7 K, thereby paving the way for future single-molecule studies of this motorized nanocar atop planar substrates.