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  Conformation of the ethoxy group in 4-ethoxy-4'-cyanobiphenyl

Emsley, J. W., Horne, T. J., Celebre, G., Longeri, M., & Zimmermann, H. (1992). Conformation of the ethoxy group in 4-ethoxy-4'-cyanobiphenyl. The Journal of Physical Chemistry, 96(20), 7929-7934. doi:10.1021/j100199a021.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0000-5FD7-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0000-5FD8-3
Genre: Journal Article

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JPhysChem_96_1992_7929.pdf (Any fulltext), 669KB
 
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http://pubs.acs.org/doi/pdf/10.1021/j100199a021 (Any fulltext)
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 Creators:
Emsley, James W., Author
Horne, T. J., Author
Celebre, G., Author
Longeri, M., Author
Zimmermann, Herbert1, 2, 3, 4, Author           
Affiliations:
1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
2Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              
3Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society, ou_1497749              
4Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497712              

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 Abstract: The deuterium and proton NMR spectra of samples of 4-ethoxy-4'-cyanobiphenyl dissolved in the nematic liquid crystal 4-hexyloxy-4'-cyanobiphenyl have been analyzed to yield quadrupolar splittings and dipolar couplings. The data are compared with values calculated for three models for the conformations adopted by the ethoxy group relative to the attached phenyl ring. These models are (a) a set of four, symmetry-related structures, (b) discrete, minimum-energy structures generated by jumps about the C4-0, O-C7, and C7-C8 bonds, and (c) the same as (b) except that a continuous potential is adopted for the motion about the 0-C7 bond

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Language(s): eng - English
 Dates: 1992-01-031992-06-111992-101992-10-01
 Publication Status: Issued
 Pages: 6
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 Rev. Type: Peer
 Identifiers: DOI: 10.1021/j100199a021
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Title: The Journal of Physical Chemistry
  Abbreviation : J. Phys. Chem.
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 96 (20) Sequence Number: - Start / End Page: 7929 - 7934 Identifier: ISSN: 1932-7447
CoNE: https://pure.mpg.de/cone/journals/resource/954926947766_3