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  Towards organic zeolites and inclusion catalysts : heptazine imide salts can exchange metal cations in the solid state

Savateev, A., Pronkin, S., Willinger, M. G., Antonietti, M., & Dontsova, D. (2017). Towards organic zeolites and inclusion catalysts: heptazine imide salts can exchange metal cations in the solid state. Chemistry – An Asian Journal, 12(13), 1517-1522. doi:10.1002/asia.201700209.

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 Creators:
Savateev, Aleksandr1, Author           
Pronkin, Sergey, Author
Willinger, Marc Georg2, Author           
Antonietti, Markus3, Author           
Dontsova, Dariya1, Author           
Affiliations:
1Dariya Dontsova, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1933288              
2Marc Willinger, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2364728              
3Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              

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 Abstract: Highly crystalline potassium (heptazine imides) were prepared by the thermal condensation of substituted 1,2,4- triazoles in eutectic salt melts. These semiconducting salts are already known to be highly active photocatalysts, e.g. for the visible light driven generation of hydrogen from water. Herein, we show that within the solid state structure, potassium ions can be exchanged to other metal ions while the crystal habitus is essentially preserved.

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 Dates: 2017-02-202017
 Publication Status: Issued
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 Identifiers: DOI: 10.1002/asia.201700209
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Title: Chemistry – An Asian Journal
  Other : Chem. – Asian J.
  Other : Chem. Asian J.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 12 (13) Sequence Number: - Start / End Page: 1517 - 1522 Identifier: ISSN: 1861-4728