Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT
  Reactivity of diorganotin(IV) dichlorides towards N, P, and O donor ligands: Crystal structure of [SnMe2Cl2(phendione)].

Momeni, B. Z., Kia, R., & Ghanbarzadeh, S. (2012). Reactivity of diorganotin(IV) dichlorides towards N, P, and O donor ligands: Crystal structure of [SnMe2Cl2(phendione)]. Monatshefte für Chemie, 143(11), 1479-1486. doi:10.1007/s00706-012-0733-5.

Item is

Dateien

einblenden: Dateien
ausblenden: Dateien
:
2375965.pdf (Verlagsversion), 550KB
 
Datei-Permalink:
-
Name:
2375965.pdf
Beschreibung:
-
OA-Status:
Sichtbarkeit:
Eingeschränkt (UNKNOWN id 303; )
MIME-Typ / Prüfsumme:
application/pdf
Technische Metadaten:
Copyright Datum:
-
Copyright Info:
-
Lizenz:
-

Externe Referenzen

einblenden:

Urheber

einblenden:
ausblenden:
 Urheber:
Momeni, B. Z., Autor
Kia, R.1, Autor           
Ghanbarzadeh, S., Autor
Affiliations:
1Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society, ou_578564              

Inhalt

einblenden:
ausblenden:
Schlagwörter: -
 Zusammenfassung: The reactions of diorganotin(IV) dichlorides SnR2Cl2 (R = Me, n-Bu) with a series of ligands having N, P, or O donor atoms have been investigated. The reaction of SnR2Cl2 (R = Me, n-Bu) with the bidentate chelating pyridyl ligands of phendione (1,10-phenanthroline-5,6-dione) and ndppz (11-nitrodipyrido[3,2-a:2′,3′-c]phenazine) affords new hexa-coordinated 1:1 adducts with general formula SnR2Cl2L (R = Me, n-Bu; L = phendione, ndppz). On the other hand, SnMe2Cl2 reacted with xantphos [9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene] to yield the hexa-coordinated 1:2 adduct [SnMe2Cl2(xantphos)2] in the solid state. However, it dissociates in solution to give the penta-coordinated 1:1 complex [SnMe2Cl2(xantphos)]. Notably, the analogous n-Bu derivative does not react, even under forcing conditions. Finally, the tin(IV) compounds SnR2Cl2 (R = Me, n-Bu) react with dppap [2-(diphenylphosphinoamino)pyridine] to give the penta-coordinated 1:1 adducts [SnR2Cl2(dppap)] (R = Me, n-Bu). The resulting complexes have been characterized by nuclear magnetic resonance (NMR) spectroscopy and elemental analysis. The X-ray crystal structure determination of [SnMe2Cl2(phendione)] reveals that the compound crystallized with two independent molecules in the asymmetric unit with a trans-[SnMe2] configuration.

Details

einblenden:
ausblenden:
Sprache(n): eng - English
 Datum: 2012-03-282012-11
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1007/s00706-012-0733-5
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: Monatshefte für Chemie
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 143 (11) Artikelnummer: - Start- / Endseite: 1479 - 1486 Identifikator: -