Deutsch
 
Hilfe Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

DATENSATZ AKTIONENEXPORT
  A large family of filled skutterudites stabilized by electron count

Luo, H., Krizan, J. W., Muechler, L., Haldolaarachchige, N., Klimczuk, T., Xie, W., et al. (2015). A large family of filled skutterudites stabilized by electron count. Nature Communications, 6: 6489, pp. 1-10. doi:10.1038/ncomms7489.

Item is

Externe Referenzen

einblenden:

Urheber

einblenden:
ausblenden:
 Urheber:
Luo, Huixia1, Autor
Krizan, Jason W.1, Autor
Muechler, Lukas2, Autor           
Haldolaarachchige, Neel1, Autor
Klimczuk, Tomasz1, Autor
Xie, Weiwei1, Autor
Fuccillo, Michael K.1, Autor
Felser, Claudia3, Autor           
Cava, Robert J.1, Autor
Affiliations:
1External Organizations, ou_persistent22              
2Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              
3Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863429              

Inhalt

einblenden:
ausblenden:
Schlagwörter: -
 Zusammenfassung: The Zintl concept is important in solid-state chemistry to explain how some compounds that combine electropositive and main group elements can be stable at formulas that at their simplest level do not make any sense. The electronegative elements in such compounds form a polyatomic electron-accepting molecule inside the solid, a 'polyanion', that fills its available energy states with electrons from the electropositive elements to obey fundamental electron-counting rules. Here we use this concept to discover a large family of filled skutterudites based on the group 9 transition metals Co, Rh, and Ir, the alkali, alkaline-earth, and rare-earth elements, and Sb-4 polyanions. Forty-three new filled skutterudites are reported, with 63 compositional variations-results that can be extended to the synthesis of hundreds of additional new compounds. Many interesting electronic and magnetic properties can be expected in future studies of these new compounds.

Details

einblenden:
ausblenden:
Sprache(n): eng - English
 Datum: 2015-03-06
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: ISI: 000352719300002
DOI: 10.1038/ncomms7489
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: Nature Communications
  Kurztitel : Nat. Commun.
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: London : Nature Publishing Group
Seiten: - Band / Heft: 6 Artikelnummer: 6489 Start- / Endseite: 1 - 10 Identifikator: ISSN: 2041-1723
CoNE: https://pure.mpg.de/cone/journals/resource/2041-1723