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  High-frequency 263 GHz PELDOR.

Tkach, I., Halbmair, K., Höbartner, C., & Bennati, M. (2014). High-frequency 263 GHz PELDOR. Applied Magnetic Resonance, 45(10), 969-979. doi:10.1007/s00723-014-0581-z.

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Tkach, I.1, Author           
Halbmair, K.1, Author           
Höbartner, C.2, Author           
Bennati, M.1, Author           
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1Research Group of Electron Paramagnetic Resonance, MPI for biophysical chemistry, Max Planck Society, ou_578606              
2Research Group of Nucleic Acid Chemistry, MPI for biophysical chemistry, Max Planck Society, ou_578605              

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 Abstract: Pulsed electron-electron double resonance (PELDOR/DEER) at high frequencies can provide information on the relative orientation of paramagnetic centres or spin labels, if those are rigidly oriented in a host biomolecule and experiments are performed with sufficient orientation selectivity. We present the first comparative PELDOR study at 263 and 94 GHz on a model RNA system containing rigid nitroxides. We show that at 263 GHz still considerable modulation depth is observed and orientation selectivity is significant, particularly in g (x)-g (y) plane of the nitroxides.

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Language(s): eng - English
 Dates: 2014-09-112014-10
 Publication Status: Issued
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 Rev. Type: Peer
 Identifiers: DOI: 10.1007/s00723-014-0581-z
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Title: Applied Magnetic Resonance
Source Genre: Journal
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Pages: - Volume / Issue: 45 (10) Sequence Number: - Start / End Page: 969 - 979 Identifier: -