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  Coulomb explosion of diatomic molecules in intense XUV fields mapped by partial covariance

Kornilov, O., Eckstein, M., Rosenblatt, M., Schulz, C. P., Motomura, K., Rouzée, A., et al. (2013). Coulomb explosion of diatomic molecules in intense XUV fields mapped by partial covariance. Journal of Physics B, 48(16): 164028, pp. 1-11. doi:10.1088/0953-4075/46/16/164028.

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Kornilov, O, Author
Eckstein, M, Author
Rosenblatt, M, Author
Schulz, C P, Author
Motomura, K, Author
Rouzée, A, Author
Klei, J, Author
Foucar, Lutz1, Author           
Siano, M, Author
Lübcke, A, Author
Schapper, F, Author
Johnsson, P, Author
Holland, D M P, Author
Schlathölter, T, Author
Marchenko, T, Author
Düsterer, S, Author
Ueda, K, Author
Vrakking, M J J, Author
Frasinski, L J, Author
Affiliations:
1Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              

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 Abstract: Single-shot time-of-flight spectra for Coulomb explosion of N2 and I2 molecules have been recorded at the Free Electron LASer in Hamburg (FLASH) and have been analysed using a partial covariance mapping technique. The partial covariance analysis unravels a detailed picture of all significant Coulomb explosion pathways, extending up to the N4+–N5+ channel for nitrogen and up to the I8+–I9+ channel for iodine. The observation of the latter channel is unexpected if only sequential ionization processes from the ground state ions are considered. The maximum kinetic energy release extracted from the covariance maps for each dissociation channel shows that Coulomb explosion of nitrogen molecules proceeds much faster than that of the iodine. The N2 ionization dynamics is modelled using classical trajectory simulations in good agreement with the outcome of the experiments. The results suggest that covariance mapping of the Coulomb explosion can be used to measure the intensity and pulse duration of free-electron lasers.

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Language(s): eng - English
 Dates: 2013-04-152013-06-142013-08-132013-08-28
 Publication Status: Issued
 Pages: 11
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1088/0953-4075/46/16/164028
Other: 7961
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Title: Journal of Physics B
Source Genre: Journal
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Pages: - Volume / Issue: 48 (16) Sequence Number: 164028 Start / End Page: 1 - 11 Identifier: ISSN: 0953-4075
CoNE: https://pure.mpg.de/cone/journals/resource/954928494403