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  Deuterium magnetic resonance in the discotic columnar mesophases of hexaalkyloxytriphenylenes: The conformation of the aliphatic side chains

Goldfarb, D., Luz, Z., & Zimmermann, H. (1983). Deuterium magnetic resonance in the discotic columnar mesophases of hexaalkyloxytriphenylenes: The conformation of the aliphatic side chains. The Journal of Chemical Physics, 78(12), 7065-7072. doi:10.1063/1.444749.

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JChemPhys_78_1983_7065.pdf (Any fulltext), 542KB
 
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 Creators:
Goldfarb, Daniella, Author
Luz, Zeev, Author
Zimmermann, Herbert1, 2, 3, 4, Author           
Affiliations:
1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
2Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              
3Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society, ou_1497749              
4Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497712              

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 Abstract: Deuterium NMR spectra of chain perdeuterated hexa‐pentyloxy, ‐hexyloxy, ‐heptyloxy, and ‐octyloxy triphenylene (THE5, THE6, THE7, and THE8) were studied as functions of temperature in the mesophase region. The deuterium quadrupole splittings exhibited several characteristic features, in particular a steplike decrease in the splitting along the alkyl chain and an even–odd alteration in the methyl splittings within the homologous series. The results are interpreted in terms of possible conformational distributions of the alkyl chain. It is found that there is bending of the alkyl chains out of the aromatic plane, and a considerable degree of chain disorder.

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Language(s): eng - English
 Dates: 1982-08-091982-09-151983
 Publication Status: Issued
 Pages: 8
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 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.444749
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Title: The Journal of Chemical Physics
  Other : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: - Volume / Issue: 78 (12) Sequence Number: - Start / End Page: 7065 - 7072 Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226