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  Axial–biaxial phase transition in discotic liquid crystals, studied by deuterium NMR

Goldfarb, D., Belsky, I., Luz, Z., & Zimmermann, H. (1983). Axial–biaxial phase transition in discotic liquid crystals, studied by deuterium NMR. The Journal of Chemical Physics, 79(12), 6203-6210. doi:10.1063/1.445804.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-AFB4-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0000-D8AC-B
Genre: Journal Article

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JChemPhys_79_1983_6203.pdf (Any fulltext), 541KB
 
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 Creators:
Goldfarb, Daniella, Author
Belsky, I., Author
Luz, Zeev, Author
Zimmermann, Herbert1, 2, 3, 4, Author           
Affiliations:
1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
2Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              
3Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society, ou_1497749              
4Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497712              

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 Abstract: Truxenehexaalkanoates (TxHAn) exhibit a variety of discotic mesophases including the sequence ND⇄Drd⇄Dho. The ordering characteristics of these phases were studied by deuterium NMR of deuterated solutes, in particular C6D6. The results indicate that during the phase transition the minor susceptibility axis of the Drd phase transforms into the director axis of the axial phases. It is suggested that in the Drd phase, in alternating columns the mesogen molecules are tilted with respect to the columns axes in opposite directions.

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Language(s): eng - English
 Dates: 1983-05-171983-06-031983-06
 Publication Status: Issued
 Pages: 8
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 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.445804
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Title: The Journal of Chemical Physics
  Other : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: - Volume / Issue: 79 (12) Sequence Number: - Start / End Page: 6203 - 6210 Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226