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  Photon-echo experiments on singlet-triplet transitions in organic mixed crystals

Wäckerle, G., Zimmermann, H., & Dinse, K. (1984). Photon-echo experiments on singlet-triplet transitions in organic mixed crystals. Chemical Physics Letters, 110(2), 107-111. doi:10.1016/0009-2614(84)80157-8.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-AF8E-9 Version Permalink: https://hdl.handle.net/21.11116/0000-0000-D56A-9
Genre: Journal Article

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ChemPhysLett_110_1984_107.pdf (Any fulltext), 420KB
 
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 Creators:
Wäckerle, G., Author
Zimmermann, Herbert1, 2, 3, 4, Author           
Dinse, Klaus−Peter, Author
Affiliations:
1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
2Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              
3Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society, ou_1497749              
4Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497712              

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 Abstract: The homogeneous optical linewidth of a spin-forbidden So → T1 transition in a chemically mixed organic crystal was directly measured in a two-pulse photon-echo experiment. The experimental values of T2Opt for the system dibromobenzophenone in dibromodiphenyl ether ranged from 1.4(3) to 3.8(2) μs, depending on the nuclear spins of the host. A temperature-dependent contribution to (T2Opt)−1 revealed an activation energy ΔE of 13.8(5) cm−1, which is tentatively attributed to a librational mode frequency.

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Language(s): eng - English
 Dates: 1984-06-291984-07-211984-09-21
 Publication Status: Issued
 Pages: 5
 Publishing info: -
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 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0009-2614(84)80157-8
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Title: Chemical Physics Letters
  Other : Chem. Phys. Lett.
Source Genre: Journal
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Publ. Info: Amsterdam : North-Holland
Pages: - Volume / Issue: 110 (2) Sequence Number: - Start / End Page: 107 - 111 Identifier: ISSN: 0009-2614
CoNE: https://pure.mpg.de/cone/journals/resource/954925389241