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Zusammenfassung:
The electronic and optical properties of the cubic perovskite, BaSnO3,
are compared with the well-known transparent conducting oxides (TCOs),
SnO2 and In2O3. The optical band gaps of the undoped compounds, as
measured by diffuse reflectance spectroscopy on powdered samples, are
3.1 eV for BaSnO3 and 3.8 eV for SnO2. Electronic structure calculations
show that both compounds possess a large conduction band dispersion,
which suggests that BaSnO3, like SnO2, should be a good TCO if it can be
n-doped. To explore this possibility the properties of substitutionally
doped, BaSn1-xSbxO3 samples were investigated. The electrical
conductivity increases drastically for BaSn1-xSbxO3 samples with x <=
0.05, showing a transition from an insulating to a metallic state. For
higher doping levels, 0.05 < x < 0.15, the conductivity saturates at 4 S
cm(-1). This is accompanied by saturation in the expansion of the cubic
lattice parameter. The color of the pellets changed from white (x = 0)
to bluish black (x = 0.15). This darkening originates from the formation
of an intense and broad optical absorption band centered at 1200-1300 nm
for the more highly doped samples. This absorption band spans both the
visible and the near-infrared regions, resulting in a loss of
transparency. Various spectroscopic techniques were used to elucidate
the observed behavior. Mossbauer spectroscopy reveals the presence of
mixed valent antimony, Sb3+(5s(2))/Sb5+(5s(0)), as x increases. ESR
spectra collected on a BaSn0.99Sb0.01O3 sample indicate that only
similar to 5% of unpaired electrons are present as delocalized carriers.
The other 95% are localized to form a Sn3+ trapped electron center. To
explain the tendency for carrier localization in doped BaSnO3 a
mechanism based on strong electron-phonon interactions in perovskites
containing cations with (n - 1)d(10)ns(0) electronic configuration is
proposed. This mechanism explains why BaSn1-xSbxO3 possesses relatively
poor TCO characteristics, in sharp contrast to widely used TCO materials
Sn1-xSbxO2 and In1-xSnxO1.5.
