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  Spectroscopic and microscopic study of vanadium oxide nanotubes

Gloskovskii, A., Nepijko, S. A., Schönhense, G., Therese, H. A., Reiber, A., Kandpal, H. C., et al. (2007). Spectroscopic and microscopic study of vanadium oxide nanotubes. Journal of Applied Physics, 101(8): 084301, pp. 1-6. doi:10.1063/1.2716157.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0018-8068-2 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0018-8070-E
Genre: Journal Article

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Gloskovskii, A.1, Author
Nepijko, S. A.1, Author
Schönhense, G.1, Author
Therese, H. A.1, Author
Reiber, A.1, Author
Kandpal, H. C.1, Author
Fecher, G. H.1, Author
Felser, C.2, Author           
Tremel, W.1, Author
Klimenkov, M.1, Author
Affiliations:
1external, ou_persistent22              
2External Organizations, ou_persistent22              

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 Abstract: V(2)O(5) nanotubes synthesized via the sol-gel route has been studied by electron energy loss spectroscopy (EELS), x-ray absorption spectroscopy (XAS), and energy dispersive x-ray analysis, in order to understand the local structure of vanadium in the nanotubes. Contrary to our expectation, all the features of the XAS and EELS spectra of the V(2)O(5) nanotubes are in line with that of bulk layered vanadium oxide revealing that vanadium is present in the 5(+) oxidation state in the nanotubes. However, V(2)O(5) nanotubes exhibit additional surface states in their electronic structure in comparison with bulk V(2)O(5). A comparison of measured and calculated spectra allows us to distinguish single-wall from multiwall V(2)O(5) nanotubes. (c) 2007 American Institute of Physics.

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 Dates: 2007-04-15
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000246072200125
DOI: 10.1063/1.2716157
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Title: Journal of Applied Physics
Source Genre: Journal
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Publ. Info: New York, NY : American Institute of Physics
Pages: - Volume / Issue: 101 (8) Sequence Number: 084301 Start / End Page: 1 - 6 Identifier: ISSN: 0021-8979
CoNE: https://pure.mpg.de/cone/journals/resource/991042723401880