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  Hidden flexibility of strychnine.

Schmidt, M., Reinscheid, F., Sun, H., Abromeit, H., Scriba, G. K. E., Soennichsen, F. D., et al. (2014). Hidden flexibility of strychnine. European Journal of Organic Chemistry, 2014(6), 1147-1150. doi:10.1002/ejoc.201301760.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0017-BF53-8 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-CBDF-D
Genre: Journal Article

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http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201301760/pdf (Publisher version)
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 Creators:
Schmidt, M.1, Author           
Reinscheid, F.1, Author           
Sun, H.1, Author           
Abromeit, H., Author
Scriba, G. K. E., Author
Soennichsen, F. D., Author
John, M., Author
Reinscheid, U. M.1, Author           
Affiliations:
1Department of NMR Based Structural Biology, MPI for Biophysical Chemistry, Max Planck Society, ou_578567              

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Free keywords: Conformation analysis; NMR spectroscopy; Density functional calculations; Dynamic stereochemistry; Natural products
 Abstract: The prototypic molecule for conformational rigidity, that is, strychnine, exhibits fast conformational exchange on the NMR timescale at room temperature. A comprehensive description of this up-to-now-hidden stereodynamic behavior is presented, which combines experimental and computational data.

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Language(s): eng - English
 Dates: 2014-01-152014-02
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/ejoc.201301760
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Title: European Journal of Organic Chemistry
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Source Genre: Journal
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Pages: - Volume / Issue: 2014 (6) Sequence Number: - Start / End Page: 1147 - 1150 Identifier: -