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  (6r,7r)4,5,6,7-H-2(4) -palmitoate and (8S,9R)-[8,9-H-2(2)]-L-erythro-sphinganine: Probes for the analysis of the stereochemical course of Delta(6)-desaturases from plants and insects

Thum, O., Hertweck, C., Simon, H., & Boland, W. (1999). (6r,7r)4,5,6,7-H-2(4) -palmitoate and (8S,9R)-[8,9-H-2(2)]-L-erythro-sphinganine: Probes for the analysis of the stereochemical course of Delta(6)-desaturases from plants and insects. Synthesis, (12), 2145-2150.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-A401-1 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0012-A402-0
Genre: Journal Article

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BOL025.pdf (Publisher version), 0B
 
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 Creators:
Thum, O.1, Author           
Hertweck, C.1, Author           
Simon, H., Author
Boland, W.1, Author           
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1Department of Bioorganic Chemistry, MPI for Chemical Ecology, Max Planck Society, ou_24028              

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Free keywords: Asymmetric reduction of (e)-alk-2-enoates Chirally deuterated sphingosines Chirally deuterated palmitic acid Cuprate mediated alkylation Oxidations Wittig reactions Lipids. D-erythro-sphingosine Sex-pheromone Fatty-acids Threo-sphingosine Biosynthesis Desaturase Identification Lepidoptera Sphingolipids Saturniidae. Chemistry & Analysis in Current Contents(R)/Life Sciences. Organic Chemistry/Polymer Science in Current Contents(R)/Physical, Chemical & Earth Sciences.
 Abstract: The stereospecifically labelled (6R,7R)-[4,5,6,7-H-2(4)]-palmitic acid (14) and (8S,9R)-[8,9-H-2(2)]-L-erythro-sphinganine (10) have been prepared in good yield from (E)-[2,3-H-2(2)]-dodec-2-enoate 5 via biocatalytic reduction with broken cells of Clost

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 Dates: 1999
 Publication Status: Issued
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 Identifiers: Other: BOL025
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Title: Synthesis
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Source Genre: Journal
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Pages: - Volume / Issue: (12) Sequence Number: - Start / End Page: 2145 - 2150 Identifier: -