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  Microsolvation of phthalocyanine molecules in superfluid helium nanodroplets as revealed by the optical line shape at electronic origin

Fuchs, S., Fischer, J., Slenczka, A., Karra, M., & Friedrich, B. (2018). Microsolvation of phthalocyanine molecules in superfluid helium nanodroplets as revealed by the optical line shape at electronic origin. The Journal of Chemical Physics, 148(14): 144301. doi:10.1063/1.5022006.

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1801.03679.pdf (Preprint), 251KB
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 Creators:
Fuchs, Stefan1, Author
Fischer, Johannes1, Author
Slenczka, Alkwin1, Author
Karra, Mallikarjun2, Author           
Friedrich, Bretislav2, Author           
Affiliations:
1Institut für Physikalische und Theoretische Chemie, Universität Regensburg, 93053 Regensburg, Germany, ou_persistent22              
2Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              

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 Abstract: We investigate the solvent shift of phthalocyanine (Pc) doped into superfluid helium droplets and probed by optical spectroscopy at the electronic origin. Our present work complements extant studies and provides results that in part contradict previous conclusions. In particular, the solvent shift does not increase monotonously with droplet radius all the way up to the bulk limit, but exhibits just the reverse dependence instead. Moreover, a substructure is resolved, whose characteristics depend on the droplet size. This behavior can hardly be reconciled with that of a freely rotating Pc-helium complex.

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Language(s): eng - English
 Dates: 2018-01-102018-03-202018-04-092018-04-14
 Publication Status: Issued
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.5022006
arXiv: 1801.03679
 Degree: -

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Title: The Journal of Chemical Physics
  Other : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: - Volume / Issue: 148 (14) Sequence Number: 144301 Start / End Page: - Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226