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  ThPt3+xBe (x=0.08): Crystal Structure and Physical Properties

Gumeniuk, R., Kohout, M., Schnelle, W., Burkhardt, U., Zschornak, M., & Leithe-Jasper, A. (2017). ThPt3+xBe (x=0.08): Crystal Structure and Physical Properties. European Journal of Inorganic Chemistry, 2017(1), 179-185. doi:10.1002/ejic.201601237.

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Gumeniuk, Roman1, Autor           
Kohout, Miroslav2, Autor           
Schnelle, Walter3, Autor           
Burkhardt, Ulrich4, Autor           
Zschornak, Matthias5, Autor
Leithe-Jasper, Andreas6, Autor           
Affiliations:
1Roman Gumeniuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863421              
2Miroslav Kohout, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863417              
3Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441              
4Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
5External Organizations, ou_persistent22              
6Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863406              

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 Zusammenfassung: ThPt3+xBe (x = 0.08) is synthesized by arc melting of a mixture of the elements. It crystallizes with its own type of structure [space group I4/mmm (No. 139), a = 7.7370(4), c = 11.4990(6) angstrom], which can be related to the cubic Ru3Sn7 and W2Cr21C6 types. Measurements of magnetic susceptibility, electrical resistivity and specific heat indicate ThPt3+xBe (x = 0.08) to be a diamagnet [chi(0) = -9.0(3) x 10(-6) emu mol(-1)] with metallic electrical resistivity, in good agreement with the calculated electronic structure [N(E-F) = 3.2 states eV(-1) f.u.(-1)]. A chemical bonding analysis was performed by the QTAIM and ELI-D approaches.

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Sprache(n): eng - English
 Datum: 2017-01-142017-01-14
 Publikationsstatus: Erschienen
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 Ort, Verlag, Ausgabe: -
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 Identifikatoren: DOI: 10.1002/ejic.201601237
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Titel: European Journal of Inorganic Chemistry
  Andere : Eur. J. Inorg. Chem.
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Weinheim, Germany : Wiley-VCH
Seiten: - Band / Heft: 2017 (1) Artikelnummer: - Start- / Endseite: 179 - 185 Identifikator: ISSN: 1434-1948
CoNE: https://pure.mpg.de/cone/journals/resource/954926953810_1