English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
  Hydrothermal Carbon Enriched with Oxygenated Groups from Biomass Glucose as an Efficient Carbocatalyst

Wen, G., Wang, B., Wang, C., Wang, J., Tian, Z., Schlögl, R., et al. (2017). Hydrothermal Carbon Enriched with Oxygenated Groups from Biomass Glucose as an Efficient Carbocatalyst. Angewandte Chemie International Edition, 56(2), 600-604. doi:10.1002/anie.201609047.

Item is

Files

show Files
hide Files
:
Manuscript.pdf (Any fulltext), 549KB
Name:
Manuscript.pdf
Description:
-
OA-Status:
Green
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
2017
Copyright Info:
Wiley-VCH
License:
-
:
Supporting information.pdf (Supplementary material), 2MB
Name:
Supporting information.pdf
Description:
-
OA-Status:
Green
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
2017
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Wen, Guodong1, Author
Wang, Bolun1, Author
Wang, Congxin2, Author
Wang, Jia1, Author
Tian, Zhijian2, Author
Schlögl, Robert3, Author           
Su, Dang Sheng1, 2, Author           
Affiliations:
1Shenyang National Laboratory for Materials Science Institute of Metal Research, Chinese Academy of Science, ou_persistent22              
2Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023 (China), ou_persistent22              
3Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

Content

show
hide
Free keywords: -
 Abstract: Metal-free carbocatalysts enriched with specific oxygenated groups with different morphology and size were synthesized from glucose by hydrothermal carbonization, in which cheap and widely available biomass could be converted into functionalized carbon using an environmentally benign process. The hydroxy- and carbonyl-enriched hydrothermal carbon (HTC) could be used in nitrobenzene reduction, and higher conversion was obtained on the sphere morphology with smaller size. In the Beckmann rearrangement of cyclohexanone oxime, carboxyl-enriched HTC exhibited superior performance compared with conventional solid acid (such as HY and HZSM-5), on which the strong acid sites and weak Lewis acid sites lead to high selectivity for the side product. Although the intrinsic acidity of carbon is weak, the carboxyl-enriched carbon was used in weak Brønsted acid-catalyzed reactions, such as the Beckmann rearrangement.

Details

show
hide
Language(s):
 Dates: 2016-11-032016-09-152016-12-072017-01-09
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201609047
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
  Other : Angew. Chem., Int. Ed.
  Other : Angew. Chem. Int. Ed.
  Other : Angewandte Chemie, International Edition
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: 5 Volume / Issue: 56 (2) Sequence Number: - Start / End Page: 600 - 604 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851