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  Carbon nanotubes as conducting support for potential Mn-oxide electrocatalysts: Influences of pre-treatment procedures

Buller, S., Heise-Podleska, M., Pfänder, N., Willinger, M. G., & Schlögl, R. (2016). Carbon nanotubes as conducting support for potential Mn-oxide electrocatalysts: Influences of pre-treatment procedures. Journal of Energy Chemistry, 25(2), 265-271. doi:10.1016/j.jechem.2016.01.022.

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JECHEM_108_final.pdf (Any fulltext), 548KB
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JECHEM_108_final.pdf
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Copyright Date:
2016
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Elsevier/Science Press
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 Creators:
Buller, Saskia1, Author
Heise-Podleska, Marius1, Author
Pfänder, Norbert1, Author           
Willinger, Marc Georg1, 2, Author           
Schlögl, Robert1, 2, Author           
Affiliations:
1Max Planck Institute for Chemical Energy Conversion, ou_persistent22              
2Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

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 Abstract: Different oxygen and nitrogen containing functional groups were created on the surface of the multi-walled carbon nanotubes. The multi-walled carbon nanotubes were treated in ultrasonic bath with sulfuric or nitric acid. Furthermore the surface texture was modified by increase of the roughness. In particular after treatment with the oxidizing nitric acid, in comparison to the H2SO4 or ultra-sonic treated samples, craters and edges are dominating the surface structures. Manganese oxide was deposited on the multi-walled carbon nanotubes by precipitation mechanism. Various manganese oxides are formed during the deposition process. The samples were characterized by elemental analysis, microscopy, thermal analysis, Raman spectroscopy, and by the zeta potential as well as X-ray diffraction measurements. It was shown that the deposited manganese oxides are stabilized rather by surface texture of the multi-walled carbon nanotubes than by created functional groups.

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 Dates: 2016-01-062015-12-092016-01-072016-01-302016-03
 Publication Status: Issued
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.jechem.2016.01.022
 Degree: -

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Title: Journal of Energy Chemistry
  Abbreviation : J. Energy Chem.
Source Genre: Journal
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Publ. Info: Amsterdam, The Netherlands : Elsevier BV
Pages: 7 Volume / Issue: 25 (2) Sequence Number: - Start / End Page: 265 - 271 Identifier: ISSN: 20954956
CoNE: https://pure.mpg.de/cone/journals/resource/20954956