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  Carbon nanotubes as conducting support for potential Mn-oxide electrocatalysts: Influences of pre-treatment procedures

Buller, S., Heise-Podleska, M., Pfänder, N., Willinger, M. G., & Schlögl, R. (2016). Carbon nanotubes as conducting support for potential Mn-oxide electrocatalysts: Influences of pre-treatment procedures. Journal of Energy Chemistry, 25(2), 265-271. doi:10.1016/j.jechem.2016.01.022.

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JECHEM_108_final.pdf (beliebiger Volltext), 548KB
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2016
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Elsevier/Science Press
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 Urheber:
Buller, Saskia1, Autor
Heise-Podleska, Marius1, Autor
Pfänder, Norbert1, Autor           
Willinger, Marc Georg1, 2, Autor           
Schlögl, Robert1, 2, Autor           
Affiliations:
1Max Planck Institute for Chemical Energy Conversion, ou_persistent22              
2Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

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 Zusammenfassung: Different oxygen and nitrogen containing functional groups were created on the surface of the multi-walled carbon nanotubes. The multi-walled carbon nanotubes were treated in ultrasonic bath with sulfuric or nitric acid. Furthermore the surface texture was modified by increase of the roughness. In particular after treatment with the oxidizing nitric acid, in comparison to the H2SO4 or ultra-sonic treated samples, craters and edges are dominating the surface structures. Manganese oxide was deposited on the multi-walled carbon nanotubes by precipitation mechanism. Various manganese oxides are formed during the deposition process. The samples were characterized by elemental analysis, microscopy, thermal analysis, Raman spectroscopy, and by the zeta potential as well as X-ray diffraction measurements. It was shown that the deposited manganese oxides are stabilized rather by surface texture of the multi-walled carbon nanotubes than by created functional groups.

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 Datum: 2016-01-062015-12-092016-01-072016-01-302016-03
 Publikationsstatus: Erschienen
 Seiten: 7
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1016/j.jechem.2016.01.022
 Art des Abschluß: -

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Titel: Journal of Energy Chemistry
  Kurztitel : J. Energy Chem.
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Amsterdam, The Netherlands : Elsevier BV
Seiten: 7 Band / Heft: 25 (2) Artikelnummer: - Start- / Endseite: 265 - 271 Identifikator: ISSN: 20954956
CoNE: https://pure.mpg.de/cone/journals/resource/20954956