Intermetallic germanides with non-centrosymmetric structures derived from the Yb
3Rh4Sn13 type

Gumeniuk, R.; Schöneich, M.; Kvashnina, K. O.; Akselrud, L.; Tsirlin, A. A.; Nicklas, M.; Schnelle, W.; Janson, O.; Zheng, Q.; Curfs, C.; Burkhardt, U.; Schwarz, U.; Leithe-Jasper, A.

doi:10.1039/c4dt03155e

Local TagsRelease HistoryDetailsSummary

Intermetallic germanides with non-centrosymmetric structures derived from the Yb₃Rh₄Sn₁₃ type

Gumeniuk, R., Schöneich, M., Kvashnina, K. O., Akselrud, L., Tsirlin, A. A., Nicklas, M., et al. (2015). Intermetallic germanides with non-centrosymmetric structures derived from the Yb₃Rh₄Sn₁₃ type. Dalton Transactions, 44(12), 5638-5651. doi:10.1039/c4dt03155e.

Item is Released

show all hide all

Basic

show hide

Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0026-C029-5 Version Permalink: https://hdl.handle.net/21.11116/0000-0000-FF0F-2

Genre: Journal Article

Files

show Files

Locators

show

Creators

show

hide

Creators:
Gumeniuk, R.¹, Author
Schöneich, M.², Author
Kvashnina, K. O.³, Author
Akselrud, L.⁴, Author
Tsirlin, A. A.⁴, Author
Nicklas, M.⁵, Author
Schnelle, W.⁶, Author
Janson, O.⁷, Author
Zheng, Q.⁴, Author
Curfs, C.³, Author
Burkhardt, U.⁸, Author
Schwarz, U.⁹, Author
Leithe-Jasper, A.¹⁰, Author

Affiliations:
1Roman Gumeniuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863421
2Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404
3External Organizations, ou_persistent22
4Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405
5Michael Nicklas, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863472
6Walter Schnelle, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863441
7Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863445
8Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422
9Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423
10Andreas Leithe-Jasper, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863406

Content

show

hide

Free keywords: -

Abstract: New germanides with composition RE3Pt4Ge13 (RE = Y, Pr, Sm, Gd, Tb, Tm) have been prepared by highpressure, high-temperature synthesis. Their crystal structures have been refined, and the relationship of this new rhombohedral and monoclinic structure types with the primitive cubic Yb3Rh4Sn13 prototype is discussed. Band structure calculations within density functional theory confirm the distorted rhombohedral and monoclinic structural arrangements to be energetically more favorable than the simple cubic one. X-ray absorption spectroscopy and magnetic susceptibility measurements indicate that the RE-atoms are in the +3 oxidation state in all studied compounds.

Details

show

hide

Language(s): eng - English

Dates: Published Online: 2015-02-23Date issued: 2015-02-23

Publication Status: Issued

Pages: -

Publishing info: -

Table of Contents: -

Rev. Type: -

Identifiers: ISI: 000351439200041
DOI: 10.1039/c4dt03155e

Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show

hide

Title: Dalton Transactions

Other : Dalton Trans.

Source Genre: Journal

Creator(s):

Affiliations:

Publ. Info: Cambridge, UK : Royal Society of Chemistry

Pages: - Volume / Issue: 44 (12) Sequence Number: - Start / End Page: 5638 - 5651 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323