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  Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins

Morandi, B., Wickens, Z. K., & Grubbs, R. H. (2013). Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins. Angewandte Chemie International Edition, 52(10), 2944-2948. doi:10.1002/anie.201209541.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0025-BA88-B Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0025-BA89-9
Genre: Journal Article

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 Creators:
Morandi, Bill1, 2, Author           
Wickens, Zachary K.1, Author
Grubbs, Robert H.1, Author
Affiliations:
1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125 (USA), ou_persistent22              
2Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              

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Free keywords: alkenes; ketones; oxidation; oxygen; palladium
 Abstract: Make it simple! A convenient and general palladium-catalyzed oxidation of internal olefins to ketones is reported. The transformation occurs at room temperature and shows wide substrate scope. Applications to the oxidation of seed-oil derivatives and a bioactive natural product are described, as well as intriguing mechanistic features.

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Language(s): eng - English
 Dates: 2013-02-272013-03-04
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201209541
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 52 (10) Sequence Number: - Start / End Page: 2944 - 2948 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833