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  The First Imidazolium-Substituted Metal Alkylidene

Occhipinti, G., Bjørsvik, H.-R., Törnroos, K. W., Fürstner, A., & Jensen, V. R. (2007). The First Imidazolium-Substituted Metal Alkylidene. Organometallics, 26(18), 4383-4385. doi:10.1021/om700590v.

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 Creators:
Occhipinti, Giovanni1, Author
Bjørsvik, Hans-René1, Author
Törnroos, Karl Wilhelm1, Author
Fürstner, Alois2, Author           
Jensen, Vidar R.1, Author
Affiliations:
1Department of Chemistry, University of Bergen, Allégaten 41, N-5007 Bergen, Norway, ou_persistent22              
2Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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 Abstract: A ruthenium complex coordinated by a bidentate aryloxy-NHC ligand has offered the first example of an imidazolium-substituted metal alkylidene, an analogue of existing phosphonium alkylidenes and metal-substituted ketenes. Investigation of the molecular structure and the quantum chemically obtained electronic structure sheds light on the nature of this new compound and the bonds central to its formation.

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Language(s): eng - English
 Dates: 2007-06-152007-07-262007-08-27
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/om700590v
 Degree: -

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Title: Organometallics
  Other : Organometallics
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 26 (18) Sequence Number: - Start / End Page: 4383 - 4385 Identifier: ISSN: 0276-7333
CoNE: https://pure.mpg.de/cone/journals/resource/954925505259