ausblenden:
Schlagwörter:
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Zusammenfassung:
A series of 2-(nitrosomethylene)-1,3-dithiole derivatives 3 have been
synthesised, and X-ray crystal structures of compounds 3g, 3h and 31
have been obtained. The coplanarity of the dithiole ring and the nitroso
group in all three compounds favours π-conjugation, and short
intramolecular oxygen...sulfur contacts (ca. 2.4 Å) occur
between the nitrosyl oxygen and a sulfur atom of the dithiole ring;
these structural features explain the stability and unreactivity of the
series of compounds 3.
