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  On the Nature of the Reactive Intermediates in Gold-Catalyzed Cycloisomerization Reactions

Fürstner, A., & Morency, L. (2008). On the Nature of the Reactive Intermediates in Gold-Catalyzed Cycloisomerization Reactions. Angewandte Chemie International Edition, 47(27), 5030-5033. doi:10.1002/anie.200800934.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-B3CA-E Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-B3CB-C
Genre: Journal Article

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anie_200800934_sm_miscellaneous_information.pdf (Supplementary material), 124KB
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https://hdl.handle.net/11858/00-001M-0000-0024-B3CC-A
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anie_200800934_sm_miscellaneous_information.pdf
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Copyright Date:
2008
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Wiley-VCH, 69451 Weinheim, Germany
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 Creators:
Fürstner, Alois1, Author           
Morency, Louis1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: carbenes; carbocations; gold; homogeneous catalysis; platinum
 Abstract: A gold rush: The Stork–Eschenmoser postulate explaining the course and stereoselectivity of cationic polyene cyclization reactions also holds true for cycloisomerization reactions catalyzed by gold. This result suggests that the pertinent intermediates (see scheme) are more adequately described as gold- stabilized carbocations rather than as gold carbenes. E=COOMe, L=neutral ligand.

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Language(s): eng - English
 Dates: 2008-02-262008-05-272008-06-23
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200800934
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag
Pages: - Volume / Issue: 47 (27) Sequence Number: - Start / End Page: 5030 - 5033 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833