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  Experimental verification of the through-bond mechanism of electron transfer in bridged donor-acceptor complexes

Pullen, S. H., Edington, M. D., Studer-Martinez, S. L., Simon, J. D., & Staab, H. A. (1999). Experimental verification of the through-bond mechanism of electron transfer in bridged donor-acceptor complexes. The Journal of Physical Chemistry A, 103(15), 2740-2743. doi:10.1021/jp984761o.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-AC59-9 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-AC5A-7
Genre: Journal Article
Alternative Title : Experimental verification of the through-bond mechanism of electron transfer in bridged donor-acceptor complexes

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JPhysChemA_103_1999_2740.pdf (Any fulltext), 102KB
 
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 Creators:
Pullen, Stuart H., Author
Edington, Maurice D., Author
Studer-Martinez, Shannon L., Author
Simon, John D., Author
Staab, Heinz A.1, Author           
Affiliations:
1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: Two rigid bischromophoric systems featuring identical donor and acceptor moieties have been studied in order to directly determine the relative importance of through−space and through−bond mechanisms for electron−transfer reactions. The two molecular systems studied have the unique feature that the through−bond distance between any pair of atoms in the two molecules is held constant while the spatial distance between the donor and acceptor is changed. Time−resolved laser measurements reveal that back−electron−transfer dynamics following photoexcitation of the ground−state charge−transfer absorption band are the same in the two systems. The results provide direct evidence for the through−bond mechanism of electron transfer in bridged organic donor−acceptor systems

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Language(s): eng - English
 Dates: 1998-12-161999-02-181999
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 666547
DOI: 10.1021/jp984761o
URI: http://pubs.acs.org/doi/abs/10.1021/jp984761o?prevSearch%3DExperimental%252BVerification%252Bof%252Bthe%252BThrough-bond%252BMechanism%252Bof%252BElectron%252BTransfer%252Bin%252BBridged%252BDonor-Acceptor%252BComplexes%26searchHistoryKey%3D
URI: http://pubs.acs.org/doi/full/10.1021/jp984761o?prevSearch%3DExperimental%252BVerification%252Bof%252Bthe%252BThrough-bond%252BMechanism%252Bof%252BElectron%252BTransfer%252Bin%252BBridged%252BDonor-Acceptor%252BComplexes%26searchHistoryKey%3D
URI: http://pubs.acs.org/doi/pdfplus/10.1021/jp984761o
Other: 4460
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Title: The Journal of Physical Chemistry A
  Other : J. Phys. Chem. A
Source Genre: Journal
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Publ. Info: Columbus, OH : American Chemical Society
Pages: - Volume / Issue: 103 (15) Sequence Number: - Start / End Page: 2740 - 2743 Identifier: ISSN: 1089-5639
CoNE: https://pure.mpg.de/cone/journals/resource/954926947766_4