Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 
4,4′-di-tert-butylbiphenyl

David, B.; Monkowius, U.; Rust, J.; Lehmann, C. W.; Hyzak, L.; Mohr, F.

doi:10.1039/C4DT00778F

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Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

David, B., Monkowius, U., Rust, J., Lehmann, C. W., Hyzak, L., & Mohr, F. (2014). Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl. Dalton Transactions, 43(28), 11059-11066. doi:10.1039/C4DT00778F.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-BFA2-8 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-BFA3-6

Genre: Journal Article

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Creators:
David, B.¹, Author
Monkowius, U.², Author
Rust, J.³, Author
Lehmann, C. W.³, Author
Hyzak, L.¹, Author
Mohr, F.³, Author

Affiliations:
1Fachbereich C, Anorganische Chemie, Bergische Universität Wuppertal, Gaußstraße 20, 42119 Wuppertal, Germany, ou_persistent22
2Institut für Anorganische Chemie, Johannes Kepler University Linz, Altenbergerstraße 69, 4040 Linz, Austria, ou_persistent22
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625

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Abstract: An oligomeric gold(III) compound containing dicarbanionic chelating 4,4′-di-tert-butylbiphenyl was prepared via transmetallation using the corresponding organotin(IV) compound. The reactivity of the chloro-bridged oligomer with various species including neutral N-, P-, and C-donor ligands as well as monoanionic S- and Se-ligands was investigated. Some of the products were characterised by X-ray crystallography. The photophysical properties of two derivatives were studied.

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Language(s): eng - English

Dates: Submitted: 2014-03-14Accepted: 2014-05-23Published Online: 2014-05-27

Publication Status: Published online

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Rev. Type: Peer

Identifiers: DOI: 10.1039/C4DT00778F

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Title: Dalton Transactions

Other : Dalton Trans.

Source Genre: Journal

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Publ. Info: Cambridge, UK : Royal Society of Chemistry

Pages: - Volume / Issue: 43 (28) Sequence Number: - Start / End Page: 11059 - 11066 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323