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  Local Characterization of Ultrathin ZnO Layers on Ag(111) by Scanning Tunneling Microscopy and Atomic Force Microscopy

Shiotari, A., Liu, B. H., Jaekel, S., Grill, L., Shaikhutdinov, S. K., Freund, H.-J., et al. (2014). Local Characterization of Ultrathin ZnO Layers on Ag(111) by Scanning Tunneling Microscopy and Atomic Force Microscopy. The Journal of Physical Chemistry C, 118(47), 27428-27435. doi:10.1021/jp509013p.

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 Creators:
Shiotari, Akitoshi1, 2, Author           
Liu, Bo Hong3, Author           
Jaekel, Simon1, Author           
Grill, Leonhard1, 4, Author           
Shaikhutdinov, Shamil K.3, Author           
Freund, Hans-Joachim3, Author           
Wolf, Martin1, Author           
Kumagai, Takashi1, Author           
Affiliations:
1Physical Chemistry, Fritz Haber Institute, Max Planck Society, ou_634546              
2Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwake-cho, 606-8502 Kyoto, Japan, ou_persistent22              
3Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              
4Universität Graz, ou_persistent22              

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 Abstract: We have studied the local structure of ultrathin ZnO layers grown on Ag(111) by the reactive deposition method using low-temperature scanning tunneling microscopy (STM) and noncontact atomic force microscopy (nc-AFM) at 5 K. The characteristic Moiré patterns arising from the lattice mismatch between the ZnO(0001) layers and Ag(111) appear in STM, but it is not pronounced in nc-AFM images. This indicates an atomically flat geometrical structure of the ZnO layer and a dominant contribution of the electronic state to the Moiré patterns imaged by STM. We found that the apparent height of STM for the ZnO layers strongly depends on the bias voltage and becomes comparable with that of nc-AFM when the bias voltage is below the conduction band edge of the ZnO layers. The ZnO layers with the STM (AFM) apparent height of 3.8 (4.0) ± 0.3 and 5.8 (6.1) ± 0.3 Å were observed. On the other hand, mapping the onset of the resonance state of the ZnO layer by scanning tunneling spectroscopy provides a basis for determining its thickness. Our results suggest that the ZnO layers on Ag(111) grow predominantly as bi- and trilayers under the conditions used.

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Language(s): eng - English
 Dates: 2014-10-152014-09-052014-11-042014-11-042014-11-26
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jp509013p
 Degree: -

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Title: The Journal of Physical Chemistry C
  Other : J. Phys. Chem. C
Source Genre: Journal
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Publ. Info: Washington DC : American Chemical Society
Pages: - Volume / Issue: 118 (47) Sequence Number: - Start / End Page: 27428 - 27435 Identifier: ISSN: 1932-7447
CoNE: https://pure.mpg.de/cone/journals/resource/954926947766