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  Catalysis by lithium perchlorate in dichloromethane: Diels-Alder reactions and 1,3-Claisen rearrangements

Reetz, M. T., & Gansäuer, A. (1993). Catalysis by lithium perchlorate in dichloromethane: Diels-Alder reactions and 1,3-Claisen rearrangements. Tetrahedron, 49(27), 6025-6030. doi:10.1016/S0040-4020(01)87187-8.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0023-CB25-5 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0023-CB26-3
Genre: Journal Article

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 Creators:
Reetz, Manfred T.1, Author           
Gansäuer, Andreas1, Author
Affiliations:
1Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445588              

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 Abstract: Lithium perchlorate suspended in dichloromethane is an efficient catalyst (4 – 25 mol-%) for stereoselective Diels-Alder, hetero-Diels-Alder and regioselective 1,3-Claisen rearrangements; this process is milder, safer and environmentally less precarious than the use of 1 – 5 molar solution of LiClO4 in ether described previously in the literature.

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Language(s): eng - English
 Dates: 2001-03-201993-07-02
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0040-4020(01)87187-8
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Title: Tetrahedron
  Other : Tetrahedron
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 49 (27) Sequence Number: - Start / End Page: 6025 - 6030 Identifier: ISSN: 0040-4020
CoNE: https://pure.mpg.de/cone/journals/resource/954925448773