On the Origin of π-Facial Diastereoselectivity in Nucleophilic Additions to 
Chiral Carbonyl Compounds 3. Rotational Profiles of 2-Methoxypropanal and 
2-N,N-Dimethylaminopropanal.

Frenking, G.; Köhler, K.F.; Reetz, Manfred T.

doi:10.1016/S0040-4020(01)89911-7

Local TagsRelease HistoryDetailsSummary

On the Origin of π-Facial Diastereoselectivity in Nucleophilic Additions to Chiral Carbonyl Compounds 3. Rotational Profiles of 2-Methoxypropanal and 2-N,N-Dimethylaminopropanal.

Frenking, G., Köhler, K., & Reetz, M. T. (1993). On the Origin of π-Facial Diastereoselectivity in Nucleophilic Additions to Chiral Carbonyl Compounds 3. Rotational Profiles of 2-Methoxypropanal and 2-N,N-Dimethylaminopropanal. Tetrahedron, 49(19), 3971-3982. doi:10.1016/S0040-4020(01)89911-7.

Item is Released

show all hide all

Basic

show hide

Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0023-CAF7-4 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0023-CAF8-2

Genre: Journal Article

Files

show Files

Locators

show

Creators

show

hide

Creators:
Frenking, G.^{1, 2}, Author
Köhler, K.F.^{1, 2}, Author
Reetz, Manfred T.^{1, 2}, Author

Affiliations:
1Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445588
2Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, D-W-3550 Marburg, Germany, ou_persistent22

Content

show

hide

Free keywords: -

Abstract: The rotational profiles of 2-methoxypropanal and 2-N,N-dimethylaminopropanal are theoretically predicted using ab initio methods at the MP2/6-31G(d)//3-21G level of theory. The conformational energies show a strong dependence on the torsion angle not only around the CπC bond but also around the CπR (R=OMe, NMe₂) bond.

Details

show

hide

Language(s):

Dates: Published Online: 2001-04-23Date issued: 1993-05-07

Publication Status: Issued

Pages: -

Publishing info: -

Table of Contents: -

Rev. Type: Peer

Identifiers: DOI: 10.1016/S0040-4020(01)89911-7

Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show

hide

Title: Tetrahedron

Other : Tetrahedron

Source Genre: Journal

Creator(s):

Affiliations:

Publ. Info: Oxford : Pergamon

Pages: - Volume / Issue: 49 (19) Sequence Number: - Start / End Page: 3971 - 3982 Identifier: ISSN: 0040-4020
CoNE: https://pure.mpg.de/cone/journals/resource/954925448773