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  Structural complexity of hexagonal prismatic crystal specimens of fluorapatite-gelatine nanocomposites: A case study in biomimetic crystal research

Kniep, R., Simon, P., & Rosseeva, E. (2014). Structural complexity of hexagonal prismatic crystal specimens of fluorapatite-gelatine nanocomposites: A case study in biomimetic crystal research. Crystal Research and Technology, 49(1), 4-13. doi:10.1002/crat.201300207.

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Kniep, Rüdiger1, Autor           
Simon, Paul2, Autor           
Rosseeva, Elena3, Autor           
Affiliations:
1Rüdiger Kniep, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863437              
2Paul Simon, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863418              
3Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863404              

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 Zusammenfassung: Hexagonal prismatic crystal-like entities of fluorapatite-gelatine nanocomposites were grown by double-diffusion in gelatine gels. The Bragg pattern of the specimens (containing 2.3(3) wt.-% gelatine) is consistent with fluorapatite. TEM images together with atomistic computer simulations reveal the material to be best described as a mosaic-dominated nanocomposite superstructure. Intrinsic electric dipole fields (detected by electron holography), generated by a non-classical crystallization process of composite nanoboards (elongated platelets), cause the integration of a meso/macroscopic pattern (symmetry: 6/m) of gelatine microfibrils into the superstructure matrix.

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 Datum: 2014-01-01
 Publikationsstatus: Erschienen
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 Ort, Verlag, Ausgabe: -
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 Identifikatoren: DOI: 10.1002/crat.201300207
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Titel: Crystal Research and Technology
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Berlin, Fed. Rep. of Germany : Wiley-VCH
Seiten: - Band / Heft: 49 (1) Artikelnummer: - Start- / Endseite: 4 - 13 Identifikator: ISSN: 0232-1300
CoNE: https://pure.mpg.de/cone/journals/resource/954928496432