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  Deuterium NMR of biaxial discotic liquid crystals

Goldfarb, D., Poupko, R., Luz, Z., & Zimmermann, H. (1983). Deuterium NMR of biaxial discotic liquid crystals. The Journal of Chemical Physics, 79(8), 40335-4047. doi:10.1063/1.446272.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-AFC2-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0000-E4C2-3
Genre: Journal Article

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JChemPhys_79_1983_4035.pdf (Any fulltext), 880KB
 
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 Creators:
Goldfarb, Daniella, Author
Poupko, Raphy, Author
Luz, Zeev, Author
Zimmermann, Herbert1, 2, 3, 4, Author           
Affiliations:
1Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497705              
2Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society, ou_1497700              
3Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society, ou_1497749              
4Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society, ou_1497712              

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 Abstract: Deuterium NMR spectra of deuterated probe molecules dissolved in several discotic liquid crystals possessing biaxial mesophases are reported. The spectra exhibit typical features characteristic of biaxial phases. This is particularly manifested through the asymmetry parameter of the average quadrupole tensor. The effect is demonstrated on two types of biaxial discotic phases: (i) a rectangular Drd mesophase which appears in homologs of triphenylenehexa‐n‐alkanoates; and (ii) a tilted Dt mesophase which occurs in homologs of benzenehexa‐n‐alkanoates. The theory relating to the motional constants in biaxial phases and the asymmetry parameter of the quadrupole tensor (and other tensorial properties) is reviewed, and applied to some specific examples.

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Language(s): eng - English
 Dates: 1983-01-101983-03-141983
 Publication Status: Issued
 Pages: 13
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 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.446272
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Title: The Journal of Chemical Physics
  Other : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: - Volume / Issue: 79 (8) Sequence Number: - Start / End Page: 40335 - 4047 Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226