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  Formal Ring-Opening/Cross-Coupling Reactions of 2-Pyrones: Iron-Catalyzed Entry into Stereodefined Dienyl Carboxylates

Sun, C.-L., & Fürstner, A. (2013). Formal Ring-Opening/Cross-Coupling Reactions of 2-Pyrones: Iron-Catalyzed Entry into Stereodefined Dienyl Carboxylates. Angewandte Chemie International Edition, 52(49), 13071-13075. doi:10.1002/anie.201307028.

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anie_201307028_sm_miscellaneous_information.pdf (Supplementary material), 3MB
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anie_201307028_sm_miscellaneous_information.pdf
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Supporting Information
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Public
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application/pdf / [MD5]
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Copyright Date:
2013
Copyright Info:
Wiley-VCH 69451 Weinheim, Germany
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 Creators:
Sun, Chang-Liang1, Author           
Fürstner, Alois1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: cross-coupling; dienes; heterocycles; iron; natural products
 Abstract: Open access: Despite the exceptional level of sophistication in cross-coupling chemistry, reactions of substrates that incorporate the leaving group as an integral part into a heterocyclic scaffold are scarce. The title reaction outlines the utility of this reaction format (see scheme; acac=acetylacetonate), provides a convenient entry into stereodefined diene carboxylates, and adds a new chapter to the field of iron catalysis.

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Language(s): eng - English
 Dates: 2013-09-032013-08-092013-10-102013-12-02
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201307028
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: 5 Volume / Issue: 52 (49) Sequence Number: - Start / End Page: 13071 - 13075 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/201310171