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  Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation

Ostapowicz, T. G., Schmitz, M., Krystof, M., Klankermayer, J., & Leitner, W. (2013). Carbon Dioxide as a C1 Building Block for the Formation of Carboxylic Acids by Formal Catalytic Hydrocarboxylation. Angewandte Chemie International Edition, 52(46), 12119-12123. doi:10.1002/anie.201304529.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-C9E3-E Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-C9E4-C
Genre: Journal Article

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anie_201304529_sm_miscellaneous_information.pdf (Supplementary material), 4MB
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https://hdl.handle.net/11858/00-001M-0000-0014-C9E5-A
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anie_201304529_sm_miscellaneous_information.pdf
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Supporting Information
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Copyright Date:
2013
Copyright Info:
Wiley-VCH 69451 Weinheim, Germany
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 Creators:
Ostapowicz, Thomas G.1, Author
Schmitz, Marc1, Author
Krystof, Monika1, Author
Klankermayer, Jürgen1, Author
Leitner, Walter1, 2, Author           
Affiliations:
1Institut für Technische und Makromolekulare Chemie RWTH Aachen University, Worringerweg 1, 52074 Aachen (Germany), ou_persistent22              
2Service Department Leitner (Technical Labs), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445626              

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Free keywords: carbon dioxide; carboxylic acids; homogeneous catalysis; hydrocarboxylation; rhodium
 Abstract: A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non-activated olefins or alcohols, CO2, and H2. Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefins results from a combination of the reverse water–gas shift (rWGS) reaction and a hydroxycarbonylation step, each promoted by a rhodium catalyst.

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Language(s): eng - English
 Dates: 2013-07-292013-05-262013-09-032013-11-11
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201304529
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angewandte Chemie - International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: 5 Volume / Issue: 52 (46) Sequence Number: - Start / End Page: 12119 - 12123 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/201310171