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  Palladium-Catalyzed Allylic Substitution at Four-Membered-Ring Systems: Formation of η1-Allyl Complexes and Electrocyclic Ring Opening

Audisio, D., Gopakumar, G., Xie, L., Alves, L. G., Wirtz, C., Martins, A. M., et al. (2013). Palladium-Catalyzed Allylic Substitution at Four-Membered-Ring Systems: Formation of η1-Allyl Complexes and Electrocyclic Ring Opening. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 52(24), 6313-6316. doi:10.1002/anie.201301034.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-A35D-1 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0019-F9E4-A
Genre: Journal Article

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anie_201301034_sm_miscellaneous_information.pdf (Supplementary material), 19MB
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https://hdl.handle.net/11858/00-001M-0000-0014-A35F-E
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anie_201301034_sm_miscellaneous_information.pdf
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Miscellaneous Information
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Copyright Date:
2013
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Wiley-VCH, 69451 Weinheim, Germany
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 Creators:
Audisio, Davide1, Author           
Gopakumar, Gopinadhanpillai2, Author           
Xie, Langui1, Author           
Alves, Luís G.3, Author
Wirtz, Cornelia4, Author           
Martins, Ana M.3, Author
Thiel, Walter2, Author           
Farès, Christophe4, Author           
Maulide, Nuno1, Author           
Affiliations:
1Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              
2Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445590              
3Centro de Química Estrutural, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001 Lissabon (Portugal), ou_persistent22              
4Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445623              

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Free keywords: allyl ligands; cyclobutene; palladium; reaction mechanisms; structure determination
 Abstract: Caught in the act: A series of unique η1-allyl palladium complexes of four-membered cyclic systems bearing β-hydrogens were prepared (see structure). Their unusual structure, reactivity, and unprecedented propensity for undergoing pericyclic reactions were uncovered.

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Language(s): eng - English
 Dates: 2013-05-062013-06-10
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201301034
 Degree: -

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Title: Angewandte Chemie International Edition : a journal of the Gesellschaft Deutscher Chemiker
Source Genre: Journal
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Publ. Info: Weinheim/Bergstr. : Verlag Chemie
Pages: 4 Volume / Issue: 52 (24) Sequence Number: - Start / End Page: 6313 - 6316 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/110984073528720