English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Synthesis and catalytic performance of CeOCl in Deacon reaction

Farra, R., Girgsdies, F., Frandsen, W., Hashagen, M., Schlögl, R., & Teschner, D. (2013). Synthesis and catalytic performance of CeOCl in Deacon reaction. Catalysis Letters, 143(10), 1012-1017. doi:10.1007/s10562-013-1085-4.

Item is

Files

show Files
hide Files
:
CeOCl_Catal.Lett_rv.pdf (Any fulltext), 908KB
Name:
CeOCl_Catal.Lett_rv.pdf
Description:
-
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
2013
Copyright Info:
Elsevier
License:
-

Locators

show

Creators

show
hide
 Creators:
Farra, Ramzi1, Author           
Girgsdies, Frank1, Author           
Frandsen, Wiebke1, Author           
Hashagen , Maike, Author
Schlögl, Robert1, Author           
Teschner, Detre1, Author           
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

Content

show
hide
Free keywords: CeOCl CeO2 Deacon reaction HCl oxidation
 Abstract: Surface chlorinated CeO2 is an efficient material for HCl oxidation, which raises the question whether an oxychloride phase could be also active in the same reaction. CeOCl was synthesized by solid state reaction of cerium oxide with anhydrous cerium chloride and tested in HCl oxidation using various feed compositions at 703 K. X-ray diffraction of post-reaction samples revealed that CeOCl is unstable, in both oxygen-rich and -lean conditions. Applying oxygen over-stoichiometric feeds led to complete transformation of CeOCl into CeO2. Considerable HCl conversions were obtained only after this transformation, which confirms the essential role of bulk cerium oxide in this catalytic system.

Details

show
hide
Language(s): eng - English
 Dates: 2013-07-042013-08-072013-08-222013-10
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1007/s10562-013-1085-4
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Catalysis Letters
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: New York : Springer
Pages: - Volume / Issue: 143 (10) Sequence Number: - Start / End Page: 1012 - 1017 Identifier: ISSN: 1011-372X
CoNE: https://pure.mpg.de/cone/journals/resource/954925586300